Hi ! Buses in Italy generally operate within provinces, and San Gimignano is in the province ofSiena.
The best way to get from San Gimignano to Arezzo by bus is to take line 130 from San Gimignano, piazza San Giovanni, and get to Siena, you will arrive in Via Tozzi from where you can take the line 138 to Arezzo.
The line San Gimignno- Siena takes about 1 hour and costs 6 €.
The line Siena – Arezzo takes about 1h 20’ and costs €6.60.
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