The journey from Florence to Volterra takes about two hours. If you want to get to Volterra from Florence you will have to change bus in Colle val d’Elsa or Pontedera. The departing Sita bus station is in Via Santa Caterina da Siena 17, near the Santa Maria Novella train station.
By Colle Val D’Elsa
Line Florence – Colle Val d’Elsa is the line 131 ordinary line Florence-Siena:
Here timetables -> Florence Siena
Line Colle Val d’Elsa – Volterra is the line 770 Cpt:
770 Volterra – Colle Val d’Elsa (valid since September 2016)
Tickets are available at ticket offices of bus station, train station, cafe, newsagents and tobacconists.
From Florence to Pontedera there is a Trenitalia train or a TTIsrl bus: line Fisciano-Milano stops in Florence and Pontedera ->TTI pdf timetable (valido al 23/06/2015)
Line Pontedera – Volterra is the line 500 Cpt:
500 Pontedera – Volterra (valid since September 2015)
Versione italiana: Firenze Volterra collegamenti